reactions of co(ii) with sodium cyanotrihydroborate in the presence of a series of bidentate and some monodentate phosphines

dc.contributor.advisor	holah, d. g.
dc.contributor.advisor	hughes, a. n.
dc.contributor.author	khan, saeed iftikhar
dc.date.accessioned	2017-06-06t13:40:32z
dc.date.available	2017-06-06t13:40:32z
dc.date.created	1981
dc.date.issued	1981
dc.identifier.uri	http://knowledgecommons.lakeheadu.ca/handle/2453/2380
dc.description.abstract	the reactions between co(c10[subscript4])[subscript2].6h[subscript2]o or cocl[subscript2].6h[subscript2]o, nabh[subscript3]cn and some monodentate (pph[subscript3] and pcy[subscript3]) and a series of bidentate phosphines of the type ph[subscript2]p-(ch[subscript2])[subscriptn]-pph[subscript2] (n = 1-4) and also cis and trans ph[subscript2]p-(ch[subscript2])[subscriptn]-pph[subscript2] have been studied under a very wide range of experimental conditions. the reactions are affected by (1) the amount of nabh[subscript3]cn used, (2) the rate of addition of nabh[subscript3]cn, (3) the temperature, (4) the solvent used and (5) the reaction time. a number of cyanotrihydroborato and other complexes have been produced and others observed but not yet isolated.
dc.language.iso	en_us
dc.subject	cobalt isotopes
dc.subject	sodium cyanotrihydroborate
dc.subject	phosphenes
dc.title	reactions of co(ii) with sodium cyanotrihydroborate in the presence of a series of bidentate and some monodentate phosphines
dc.type	thesis
etd.degree.name	master of science
etd.degree.level	master
etd.degree.discipline	chemistry
etd.degree.grantor	阿根廷vs墨西哥竞猜