ruthenium piano stool complexes incorporating novel bis(pyrrolidinyl)alkylphosphines

dc.contributor.advisor	spivak, gregory
dc.contributor.author	beach, michael t.
dc.date.accessioned	2012-11-11t03:21:22z
dc.date.available	2012-11-11t03:21:22z
dc.date.created	2011-12
dc.date.issued	2012-11-10
dc.identifier.uri	http://knowledgecommons.lakeheadu.ca/handle/2453/297
dc.description.abstract	conventional phosphine ligands (i.e., those typically bearing alkyl and/or aryl substituents) have played a crucial role in the development of transition metal coordination chemistry. many structural and electronic variants have been explored, including the class of bis(n-pyrrolidinyl)alkylphosphines. these phosphines generally possess moderate steric properties, yet exhibit exceptional electron-donating properties. the greater lewis basicity of bis(n-pyrrolidinyl)alkylphosphines likely can be attributed to the additional electron density provided by the lone pair of the planar nitrogen atoms through a dative interaction with the phosphorus donor atom.	en_us
dc.language.iso	en_us	en_us
dc.subject	ruthenium piano-stool complexes	en_us
dc.subject	phosphine ligands	en_us
dc.title	ruthenium piano stool complexes incorporating novel bis(pyrrolidinyl)alkylphosphines	en_us
dc.type	thesis	en_us
etd.degree.name	m.sc.	en_us
etd.degree.level	master	en_us
etd.degree.discipline	chemistry	en_us
etd.degree.grantor	阿根廷vs墨西哥竞猜	en_us